Molecular Sieve 13X for Mercaptan Removal Process in Aerosol Industries

23:49 | Posted by | | Edit Post
Molecular sieve is extensively utilized in the process of purification of petroleum products. However, these products possess powerful compounds like hydrogen sulphide, mercaptan, carbon dioxide and water which ought to be taken away to get the unadulterated product. Since, the adsorption process is done by allowing the passage of gasoline product from the cot of zeolite for some time period according the quality of impurity needed to be taken away. The contaminants found in the adsorbent are effortlessly detached away from molecular sieve in the temperature range of 200 degree Celsius to 325 degree celsius. 13x molecular sieve based upon sodium brings perfect result while sweetening of mercaptans as well as other unnecessary compounds with the aid of purifying and drying specific types of gases and liquids.

The main objective of molecular sieve is to decrease or neglect the abundant water content to fixed level. However, 13x desiccant type X crystals shape possess pore size is very large compared to type A crystal. The aspect involved in neglecting the impurities cannot be found easily with A Type crystal since 13X is employed for specific dehydration process of taking away the mercaptan odorants from gases used in aerosol industry.  Since, it can easily absorb all kinds of materials that has molecular diameter of less than 10 angstrom. The mercaptan removal process is carried out easily from aerosol, LPG, natural gas and other hydrocarbons by making use of most specific pore size of molecular sieve type. 

Molecular sieve has the capability to adsorb the typical organic chemical found in countless of liquid and gaseous application so as to get high percent of clean and pure products at the end. While for natural gas sweetening and liquid hydrocarbons, removal of mercaptans and H2S is needed in process of dehydration to obtain the clean natural gas devoid of any sort of impurities. The molecular sieve adsorbent can be employed for wide range of applications depending upon its molecular size and shape. There are various kinds of molecular sieves beads form available like 3A, 4A, 54 and 13X. Other than beads form, the molecular sieve is also found in pellets.

The molecular sieve has been considered as the strongest adsorbents which are having powerful adsorption capacity with carbon dioxide, oxygen, water and other molecules which is less compared to its pore size. Moreover, all the molecular sieve adsorbents are available in powdered, pelleted and beaded form. The molecular sieve is a wonderful crystalline alumina silicate that has the amazing ability to serve as the adsorbent to gases and solvents. It carries out the separation and adsorbing process depending upon the size of molecules. 


Industrial Use:

  • Petrochemicals
  • Chemical Refineries
  • Natural Gas Manufacturing Industry
  • Industrial Gas Manufacturing Industry

Other Industrial Applications use of Molecular Sieve 13X:

  • Treatment of liquefied natural gas (elimination of H2O, CO, H2S and mercaptans.)
  • Sweetening of natural gas
  • Drying and purification of inert gas
  • Drying and removal of CO from air before the air liquefaction units

Labels: | 2 comments

Choice of Moisture Adsorbents for Industrial Gases

01:11 | Posted by | | Edit Post
In the industrial sector today there are many types of adsorbents which are existing; as such silica gel, activated alumina, molecular sieve and activated carbon which are more used chemical industries, refineries, oil industries and many other commercial markets. Hence user needs to make a right and economic selection of true adsorbent. From the adsorbents – alumina, silica and zeolite have a high adsorption capacity at low pressure. By virtue of their adsorption capacity these adsorbents does their job of efficient drying. In case of the high relative humidity drying condition, activated alumina is more preferable to having largest adsorb capacity. Where as in case of low relative humidity drying application at higher temperature, molecular sieve more prefer. During this process temperature can set up to 60C0
  
Molecular Sieves:

We produced natural zeolite based and alumina based adsorbent molecular sieve, containing crystalline type aluminosilicate with a clay. These adsorbent is the most suitable for their industrial drying and purification process as a true moisture adsorbent

Molecular Sieve Beads
The special features of molecular sieves are in reversible adsorption process for various gaseous compounds with having high surface area. The sodium based molecules has pore size of 4A0, indicate MS4A, with replacement of sodium by calcium based molecules having pore width 5A0, known as MS5A. In the same process replacing sodium to potassium pore size 3A0, leads to MS3A, all this molecular sieve types are zeolite type A structure. While as zeolite type X structure gives 10A based on calcium based molecular compounds, leads to MS13X, having highest adsorption capacity than other mol sieves.  

Regeneration Process:

Normally adsorbents are used in two ways one in adsorption mode and another in regeneration mode. After water and moisture saturating process reaches at the equilibrium zone, molecular sieve can restore for the adsorption process by heating temperature 270 to 295 C0 from the inert gas by changing thermal pressure or pressure swing. If fastest generation required, set temperature to 360C0
  
Separation/Purification Process:

Molecular sieve are used for industrial gas such as hydrogen, nitrogen, oxygen, carbon dioxide, etc. separation and purification process. The selection of molecular sieve types are depends on their pore diameter size and its polarity. Only those molecules having their pore size smaller than the chemicals or solvents.

Advantages:

  • Higher static and dynamic adsorption capacity
  • Regenerate under lower temperature
  • Oil, organic solvents and natural gases purification
  • Three types of intra connecting networks
  • Improved purification capability
  • Improve the life time of adsorbent
  • Improve adsorbent capacity


Labels: | 1 comments

Solid Adsorbent - Molecular Sieve for Dehydration

20:52 | Posted by | | Edit Post
In various industries, the requirements of solid adsorbents are various applications as well. There are industries and companies that require 100% water free ethanol and mainly those produce alcohol. The final product of the alcohol contains 94.6% alcohol and the remaining part is water. Now, things become tougher when it comes to removing the amount of water from the mixture and this cannot be accomplished with any straightforward process. Particular dehydration process needs to be followed for this purpose and the water needs to be extracted after dehydrating it. It is done with the help of different adsorbents and the structure of the adsorbent is molecular sieve 3a.

Molecular Sieve Pellets & Beads
More so, in this dehydration process, no chemical is used and the handling process is so safe and no chances of any danger. These sieves are not only effective to dehydrate the ethanol but also massive useful in dehydrating other types of chemicals too. The service life of this molecular desiccant is an enticing factor to use this molecular sieve. If that is not destructed because of mechanical reasons, the sieves can continue the dehydration process for more than 5 years. The best part is that this sieve can work as an individual and can be combined with other distillation system as well.

Sorbead India, you can expect an advanced molecular sieve for dehydration process. All the different variants of the sieves 3A, 4A, 5A & 13X are available at us and we have been dealing with these sieves since a long while. You can collect your preferred sieve as per your requirement from us.
Labels: | 1 comments

Molecular Sieves | Desiccants & Adsorbents

02:31 | Posted by | | Edit Post
A molecular sieve is a material with little openings of exact and uniform size. These openings are little enough to piece extensive atoms and permit little particles to pass. These sieves are a microporous material which can specifically adsorb gasses and liquids. They are manufactured zeolites (crystalline metal aluminosilicates) which upon parchedness can proficiently and specifically uproot water or different solvents. The selectivity of a molecular sieve is controlled by its pore size, atoms with a basic width which is short of what the pore size will be proficiently adsorbed while bigger particles will be avoided. The crystalline metal aluminosilicates have a three dimensional interconnecting system of silica and alumina tetrahedra. Common water of hydration is expelled from this system by warming to deliver uniform holes which specifically adsorb particles of a particular size.

The width of a molecular sieve is measured in Angstroms (Å) or nanometres (nm). The unit transformation for 1 Å is 0.1 nm. As per IUPAC documentation, microporous materials have pore breadths of short of what 2 nm (20 Å) and macroporous materials have pore distances across of more prominent than 50 nm (500 Å); the mesoporous class along these lines lies in the center with pore widths somewhere around 2 and 50 nm (20-500 Å)

Molecular sieves are utilized adsorbent for gasses and fluids. Particles little enough to pass through the pores are adsorbed while bigger atoms are definitely not. It is not quite the same as a typical channel in that it works on a molecular level and traps the adsorbed substance. Case in point, a water atom may be little enough to pass through the pores while bigger particles are not, so water is constrained into the pores which go about as a trap for the infiltrating water atoms, which are held inside the pores.

They are frequently used in the petroleum business, particularly for the decontamination of gas streams and in the science research facility for dividing mixes and drying response beginning materials. Case in point, in the fluid characteristic gas (LNG) industry, the water substance of the gas needs to be lessened to low values keep it from solidifying (and bringing on blockages) in the driving rain area of LNG plants. They are additionally utilized within the filtration of air supplies for breathing mechanical assembly, for instance those utilized by scuba jumpers and firefighters. In such applications, air is supplied by an air compressor and is passed through a cartridge channel which, subject to the application, is loaded with molecular sieve, at long last being utilized to charge breathing air tanks. Such filtration can uproot particulates and compressor deplete items from the breathing air supply.


Labels: | 0 comments

Why molecular sieve is more popular than other adsorbents?

02:17 | Posted by | | Edit Post
Molecular Sieves are popularly known as desiccants. These Sieves are used as catalyst and also as filters. The most popularly used Molecular Sieves are Activated Charcoal and Silica Gel. The size of these pores is as small as one angstrom which is equivalent to one nano meter. Molecular sieves are very popular liquid and gaseous filters which help in easy adsorption of gases and liquids. These are made up of crystalline alumino silicates having a three dimensional molecular network which helps in trapping the liquid and gaseous molecules. In gas phase processes a molecular sieve size of about 4 to 8 mesh size is usually used where as in liquid phase application a sieve of about 8 to 12 mesh size is usually used.

Petroleum industry is one of the highest consumers of molecular sieves to separate gasoline from the impurities. You would find molecular sieves in all chemical laboratories where it is used as a catalyst to fasten up the chemical process. Even fire fighters make use of this under FDA approval. Molecular sieves are the boon for manufacturing and chemical industries for its adsorption properties also used in water filters. These adsorbers could be used in various different purposes. These moleculars come in different sizes depending on use. You get 3 Angstrom and 4 Angstrom sizes which are quiet popular. These sieves have the property of demineralizing the water which makes it fit to be used for drinking purposes. These Sieves work on calcium ion exchange methodology and is now used in all water filters. Off late, these sieves have found utility in organic synthetic procedures too.

These molecular sieves are often stored at room temperature with a constant relative humidity of about 90 percent. These are prevented to come in direct contact with air, water, acid and base. Other measures required to store these adsorbents include storing in cardboard barrels. These Molecular Sieves have an amazing drying capacity even at 90 degree celcius. Molecular sieves have found many commercial uses and it has replaced long time taking chemical processes to finish in just a few seconds. These microporous sieves are also referred to as synthetic zeolites as well. These zeolites also offer different adsorption capacities based upon their molecular shapes and the affinity towards the substance to be adsorbed.


Labels:, | 2 comments
Subscribe to: Posts (Atom)

Popular Posts

Powered by Blogger.